6. Superman

This was the first officially sanctioned crossover between Marvel and DC. Spidey and Supes, head to head. Touted as both a team-up and a battle, it set the foundation for future Marvel/DC crossovers (my favorite of which is still JLA/Avengers, easily followed by The New Teen Titans and X-Men, not counting the entire Access and Amalgam stories…). It showed the 2 companies, albeit different, can work together for the enjoyment of the fans! (I wonder how this story would play out with the New 52 Supes, since we can assume Spidey would remember it still… hmmm…)

Superman VS Spider-Man

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